[Nhcoll-l] vivianite preservation
Christian Baars
Christian.Baars at museumwales.ac.uk
Tue Apr 24 04:57:49 EDT 2018
Hi Becky,
What is more important to preserve, the waterlogged wood or the vivianite?
Vivianite is an iron-phosphate mineral often associated with archaeological objects (i.e. waterlogged wood and skeletons), as it can form from the oxidation of pyrite and in association with phosphate-rich minerals (e.g. bone). Vivianite is originally clear but oxidises quickly and then turns blue. It also contains 8 molecules of crystalline water per molecule of mineral, and is therefore prone to dehydration. If waterlogged wood (which itself is preserved because it would have been buried in an anoxic environment) is exposed to the atmosphere, the oxidation and associated colour change in vivianite can happen quite quickly. Dehydration of vivianite can result in cracking and physical disintegration.
To preserve the vivianite you would need to contain it in a micro environment under high relative humidity and exclusion of oxygen.
If you were more interested in preserving the waterlogged wood, any of the usual ways for doing so (e.g., impregnation, replacement of water with non-aqueous solvents, freeze drying) would be mutually exclusive with the preservation of vivianite.
Kind regards
Christian
Dr Christian Baars AMA
Senior Preventive Conservator
National Museum Cardiff
Department of Collection Services
Cathays Park, Cardiff CF10 4NP, UK
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From: Nhcoll-l [mailto:nhcoll-l-bounces at mailman.yale.edu] On Behalf Of Becky Desjardins
Sent: 24 April 2018 07:58
To: nhcoll-l at mailman.yale.edu; Arike Gill <arike.gill at naturalis.nl>
Subject: [Nhcoll-l] vivianite preservation
Hello all;
One of our curators recently collected a sample of waterlogged wood (could be clay) with crystals of vivianite on it. Vivianite changes color when exposed to air (which is already happening) and the wood/clay is drying out. Does anyone have any tips for how to preserve it? Keep it in glycerine? Or oil? I welcome your suggestions.
Met vriendelijke groeten,
Becky Desjardins
Taxidermist/Preparator
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